Theory

Simple explanation

1. Photons in sunlight hit the solar panel and are absorbed by semiconducting materials, such as silicon.
2. Electrons (negatively charged) are knocked loose from their atoms, allowing them to flow through the material to produce electricity. Due to the special composition of solar cells, the electrons are only allowed to move in a single direction.
3. An array of solar cells converts solar energy into a usable amount of direct current (DC) electricity.

[edit] Photogeneration of charge carriers

When a photon hits a piece of silicon, one of three things can happen:

1. the photon can pass straight through the silicon — this (generally) happens for lower energy photons,
2. the photon can reflect off the surface,
3. the photon can be absorbed by the silicon, if the photon energy is higher than the silicon band gap value. This generates an electron-hole pair and sometimes heat, depending on the band structure.

When a photon is absorbed, its energy is given to an electron in the crystal lattice. Usually this electron is in the valence band, and is tightly bound in covalent bonds between neighboring atoms, and hence unable to move far. The energy given to it by the photon "excites" it into the conduction band, where it is free to move around within the semiconductor. The covalent bond that the electron was previously a part of now has one fewer electron — this is known as a hole. The presence of a missing covalent bond allows the bonded electrons of neighboring atoms to move into the "hole," leaving another hole behind, and in this way a hole can move through the lattice. Thus, it can be said that photons absorbed in the semiconductor create mobile electron-hole pairs.

A photon need only have greater energy than that of the band gap in order to excite an electron from the valence band into the conduction band. However, the solar frequency spectrum approximates a black body spectrum at ~6000 K, and as such, much of the solar radiation reaching the Earth is composed of photons with energies greater than the band gap of silicon. These higher energy photons will be absorbed by the solar cell, but the difference in energy between these photons and the silicon band gap is converted into heat (via lattice vibrations — called phonons) rather than into usable electrical energy.

Applications and implementations

Solar cells are often electrically connected and encapsulated as a module. Photovoltaic modules often have a sheet of glass on the front (sun up) side, allowing light to pass while protecting the semiconductor wafers from the elements (rain, hail, etc.). Solar cells are also usually connected in series in modules, creating an additive voltage. Connecting cells in parallel will yield a higher current. Modules are then interconnected, in series or parallel, or both, to create an array with the desired peak DC voltage and current.

The power output of a solar array is measured in watts or kilowatts. In order to calculate the typical energy needs of the application, a measurement in watt-hours, kilowatt-hours or kilowatt-hours per day is often used. A common rule of thumb is that average power is equal to 20% of peak power, so that each peak kilowatt of solar array output power corresponds to energy production of 4.8 kWh per day (24 hours x 1 kW x 20% = 4.8 kWh).

To make practical use of the solar-generated energy, the electricity is most often fed into the electricity grid using inverters (grid-connected photovoltaic systems); in stand-alone systems, batteries are used to store the energy that is not needed immediately.

Solar cells can also be applied to other electronics devices to make it self-power sustainable in the sun. There are solar cell phone chargers, solar bike light and solar camping lanterns that people can adopt for daily use.

History of solar cells

The term "photovoltaic" comes from the Greek φῶς (phōs) meaning "light", and "voltaic", meaning electric, from the name of the Italian physicist Volta, after whom a unit of electro-motive force, the volt, is named. The term "photo-voltaic" has been in use in English since 1849.^[1]

The photovoltaic effect was first recognized in 1839 by French physicist A. E. Becquerel. However, it was not until 1883 that the first solar cell was built, by Charles Fritts, who coated the semiconductor selenium with an extremely thin layer of gold to form the junctions. The device was only around 1% efficient. Subsequently Russian physicist Aleksandr Stoletov built the first solar cell based on the outer photoelectric effect (discovered by Heinrich Hertz earlier in 1887). Albert Einstein explained the photoelectric effect in 1905 for which he received the Nobel prize in Physics in 1921. Russell Ohl patented the modern junction semiconductor solar cell in 1946^[2], which was discovered while working on the series of advances that would lead to the transistor. The highly efficient solar cell was first developed by Chapin, Fuller and Pearson in 1954 using a diffused silicon p-n junction. In the past four decades, remarkable progress has been made, with Megawatt solar power generating plants having now been built.^[3]

Definition of solar cell

A solar cell is a device that converts the energy of sunlight directly into electricity by the photovoltaic effect. Sometimes the term solar cell is reserved for devices intended specifically to capture energy from sunlight such as solar panels and solar cells, while the term photovoltaic cell is used when the light source is unspecified. Assemblies of cells are used to make solar panels, solar modules, or photovoltaic arrays. Photovoltaics is the field of technology and research related to the application of solar cells in producing electricity for practical use. The energy generated this way is an example of solar energy (also known as solar power).